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Consider giving MiroTalk a try. It has several versions but the P2P version would probably be perfect for your scenario. It’s free, runs in your browser, doesn’t need an account, and doesn’t have time limit shenanigans. I’ve used it in lieu of Discord calls before and don’t have any complaints.
If you use the public instance you don’t need to set up or host or install anything. You can selfhost it if you want, but the public instance works just fine.
One person goes to the web page and starts a room. The other can join the same room by knowing the name of the room. (It will generate a link when you create a room to make it easy to send to someone so they can join by just clicking the link.)